Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa- 2,5-dienone in the presence of potassium permanganate without a co-oxidant
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چکیده
4-Allyl-4-hydroperoxy-2-methoxycyclohexa-2,5-dienone (5) was synthesized by photooxygenation of commercially available Eugenol in the presence of tetraphenylporphyrin (TPP) as a singlet oxygen sensitizer. The brief and one-pot syntheses of some natural product skeletons were conducted using the corresponding allylic hydroperoxide at different temperatures (0 o C and room temperature) with potassium permanganate (KMnO4) in mild condition at N2(g) atm.
منابع مشابه
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